高压辊磨强化铁精矿球团低温焙烧固结行为及机理
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杨永斌(1969—),男,教授,从事钢铁冶金、湿法冶金、资源综合利用方面的研究。

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TF046.6

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中国宝武低碳冶金创新基金资助项目(BWLCF202301)


Low-temperature roasting and consolidation behavior and mechanism of iron concentrate pellets driven by high-pressure roller mill
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    摘要:

    高压辊磨技术作为铁精矿预处理的重要手段,能够显著改善铁矿颗粒的物理化学特性,进而强化球团矿的成球性能与焙烧固结行为。本文以国内某钢铁企业混合铁精矿为原料,系统考察高压辊磨预处理对生球性能及焙烧球团强度的影响,并揭示其强化固结的机理。结果表明: 高压辊磨通过机械活化作用显著提高了铁精矿的细粒级占比(<0.074 mm 粒级质量分数从83.70%提升至91.77%)和比表面积(从2 424.07 cm2/g 增至3 331.60 cm2/g),从而增强颗粒间的黏附能力。适当地进行高压辊磨预处理(2次) 可有效提高生球强度,但过度辊磨(4次) 会因颗粒过细导致生球塑性下降,抗压强度降低。此外,适宜的辊磨给料水分(8%) 和膨润土用量(1.2%)可进一步优化生球性能。在焙烧过程中,高压辊磨预处理通过降低固相反应活化能,使球团在较低温度下实现高效固结。经2次辊磨制备的球团在1 110 ℃焙烧时抗压强度即可达2 599 N/P,满足生产要求; 而未处理组需1 200 ℃( 强度为3 496 N/P)才能达到生产强度要求。然而,过高的焙烧温度(>1 200 ℃) 会因过量低熔点液相的生成削弱晶桥连接,导致球团矿强度下降。高压辊磨预处理通过机械活化与颗粒表面改性,实现了球团低温高效固结( 焙烧温度降低90~100 ℃),可为钢铁行业节能减排提供理论依据与技术支撑。

    Abstract:

    As an important means of pretreatment of iron ore concentrate,high-pressure roller mill technology can significantly improve the physical and chemical properties of iron ore particles,and enhance the pelletizing performance and roasting consolidation behavior of pellets. In this paper,the effects of high-pressure roller mill pretreatment on the properties of fresh pellets and the strength of roasted pellets are systematically investigated using mixed iron concentrate from a domestic iron and steel enterprise, and the mechanism of strengthening consolidation is revealed. The results show that the proportion of fine particle size (<0.074 mm, the mass fraction of particle size is increased from 83.70% to 91.77%) and the specific surface area (from 2 424. 07 cm2/g to 3 331. 60 cm2/g) of iron concentrate by mechanical activation, and enhance the adhesion capacity between particles. Proper high-pressure roller mill pretreatment (2 times) can effectively improve the strength of the fresh pellet,but excessive roller mill (4 times) will reduce the plasticity of the fresh pellet and reduce the compressive strength due to the fineness of the particles. In addition, the appropriate roller mill feeding moisture (8%) and bentonite dosage (1.2%) can further optimize the fresh pellet performance. During the roasting process, the high-pressure roller mill pretreatment can reduce the activation energy of the solid-phase reaction, so that the pellets can be consolidated efficiently at a lower temperature. The compressive strength of the pellets prepared by two roller mills can reach 2 599 N/P when roasted at 1 110 ℃,which meets the production requirements. The untreated group needs 1 200 ℃ (strength 3 496 N/P) to meet the production strength requirements. However,excessive roasting temperatures (>1 200 ℃) can weaken the bridge connections due to the formation of excessive low melting point liquid phases, resulting in a decrease in pellet strength. The high-pressure roller mill pretreatment realizes the low-temperature and efficient consolidation of pellets ( the roasting temperature is reduced by 90~100 ℃) through mechanical activation and particle surface modification,which can provide theoretical basis and technical support for energy conservation and emission reduction in the steel industry.

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杨永斌,杨忠玉,王林,文小平,谢路奔,刘百祥.高压辊磨强化铁精矿球团低温焙烧固结行为及机理[J].工程建设,2025,50(6):38-46

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  • 收稿日期:2025-01-18
  • 最后修改日期:2025-08-15
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  • 在线发布日期: 2025-11-16
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