新疆哈密某钒钛磁铁矿球团氧化焙烧行为
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鱼灵通(1970—),男,工程师,从事冶金新技术等方面研究工作。

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TF046.6

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国家自然科学基金资助项目(52174325); 陕西省创新能力支撑计划资助项目(2023-CX-TD-53)


Study on oxidizing roasting behavior of pellets produced with a certain vanadium-titanium magnetite,Hami,Xinjiang
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    摘要:

    新疆哈密地区钒钛磁铁矿资源丰富,该铁矿用于球团生产对推动钢铁行业绿色转型具有重要的理论意义和实践价值。本文以该钒钛磁铁矿为对象,研究预热、焙烧条件对钒钛磁铁矿球团性能的影响,并利用XRD与SEM-EDS 分析其物相和微观形貌,从而揭示氧化焙烧过程中钒钛磁铁矿球团的固结机理。结果表明: 该钒钛磁铁矿球团在900 ℃预热18 min、1 250 ℃焙烧12 min的最佳工艺条件下,焙烧球的抗压强度为2 579. 61 N/P。球团的氧化固结 过程可分为氧化前、中、后期三个阶段: 前期主要发生磁铁矿与钛磁铁矿的氧化反应,球团内部孔隙较大,颗粒分布松散,抗压强度较低; 中期磁铁矿与钛磁铁矿进一步氧化生成赤铁矿和钛酸铁,钛铁矿与赤铁矿反应生成钛赤 铁矿,孔隙数量减少,球团结构趋于致密; 后期赤铁矿再结晶良好,并聚集长大,颗粒间形成高度致密结构,氧化固结过程基本完成,球团的抗压强度显著提升。本文研究成果可为球团生产工艺应用钒钛磁铁矿提供依据。

    Abstract:

    The vanadium-titanium magnetite resources in Hami area of Xinjiang are abundant; utilizing this kind of magnetite for pellet production holds significant theoretical and practical value for promoting green transformation of the iron and steel industry. In this study, the vanadium-titanium magnetite from Hami area of Xinjiang was studied on the effects of preheating and roasting conditions to the properties of pellets of vanadium-titanium magnetite and XRD and SEM-EDS was used to detect and analyze its phase composition and microstructure, thereby revealing the consolidation mechanism of the pellets of vanadium-titanium magnetite during oxidizing roasting. The results indicate that the optimal process conditions for the pellets of such vanadium-titanium magnetite are preheating at 900 ℃ for 18 min followed by roasting at 1 250 ℃ for 12 min,under which the roasted pellets achieve a compressive strength of 2 579.61 N/P. The oxidation consolidation process can be divided into three stages: In the initial stage of oxidation,magnetite and titanium magnetite undergo oxidation, resulting in large pores and loosely distributed particles with low compressive strength. In the intermediate stage of oxidation,magnetite and titanium magnetite further undergo oxidation to generate hematite and ferrous titanate,while ilmenite reacts with hematite to generate haplotypite,reducing the porosity and densifying the pellet structure. In the final stage,hematite recrystallizes well and aggregates into larger particles, forming a highly compact structure among particles,essentially completing the oxidation consolidation and significantly enhancing compressive strength of pellets. The findings of this study provide a basis for the application of vanadium-titanium magnetite in pellet production process.

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鱼灵通,项心如,巨建涛,郭文科,赵贵清,邢相栋.新疆哈密某钒钛磁铁矿球团氧化焙烧行为[J].工程建设,2025,50(6):47-55

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  • 收稿日期:2024-09-09
  • 最后修改日期:2025-06-11
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  • 在线发布日期: 2025-11-16
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