高硫铁矿氧化焙烧过程中硫的迁移行为
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谢雨时(2000—),男,硕士研究生,从事高硫铁矿造块脱硫方法的研究。

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TF046

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国家自然科学基金资助项目(52374412)


Migration behavior of sulfur during oxidative roasting of high-sulfur iron ore
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    摘要:

    凭借毗邻我国的区位优势及未充分开发的资源潜力,蒙古铁矿已成为我国重要的铁矿供应来源,但该矿含硫量较高,不能直接进入传统高炉冶炼。为探究该高硫铁矿的适用性和可行性,本文对磁选后的高硫铁精矿粉进行不同温度的氧化焙烧试验,对焙烧前后高硫铁精矿粉的物相组成、硫的赋存状态等进行分析,并结合试验温度区间内各反应的热力学分析及焙烧过程中SO2排放质量浓度的变化,得到不同温度焙烧后高硫铁精矿粉的脱硫效果及硫的迁移行为规律。结果表明:高硫铁精矿粉中含硫物相主要为黄铁矿及磁黄铁矿,二者氧化脱硫反应在试验温度范围内均可自发进行;经过1 100℃和1 200℃焙烧后矿粉的含硫量从原矿的3.186%分别降至0.034%和0.017%,脱硫率均高于98%。本文通过揭示高硫铁精矿粉在氧化焙烧过程中硫的迁移行为,证实高温氧化焙烧可实现高硫铁矿的高效脱硫,为后续造球、烧结等实际生产过程中,脱硫方法的应用提供重要的理论依据。

    Abstract:

    With the geographical advantage of being adjacent to China and underutilized resource potential,Mongolian iron ore has become a significant source of iron ore supply for China,however,it cannot be directly used in traditional blast furnace smelting due to its high sulfur content. To explore the application feasibility of this high-sulfur iron ore,this paper studies the oxidative roasting test at different temperatures conducted on magnetically separated high-sulfur iron ore concentrate powder. Through the test,the phase composition and sulfur occurrence state of the high-sulfur iron concentrate powder before and after roasting were analyzed. Combined with thermodynamic analysis of relevant reactions within the test temperature range and the change in SO2 emission mass concentration during roasting,the desulfurization effect and the pattern of sulfur migration behavior in the high-sulfur iron concentrate powder after roasting at different temperatures were obtained. The test results show that the main sulfur-bearing phases in the high-sulfur iron concentrate powder are pyrite and pyrrhotite,and the oxidative desulfurization reactions of both can proceed spontaneously within the test temperature range. After roasting at 1 100 ℃ and 1 200 ℃,the sulfur content of the ore powder decreased from 3. 186% in the raw ore to 0.034% and 0.017%,respectively,with desulfurization rates both exceeding 98%. By revealing the sulfur migration behavior in high-sulfur iron concentrate powder during oxidative roasting,this paper confirms that the high-sulfur iron ore can be efficiently desulfurized through high-temperature oxidative roasting,which provides an important theoretical basis for the application of desulfurization methods in subsequent practical production processes such as pelletizing and sintering etc.

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谢雨时,杨博文,张波,贾中帅,罗国立,魏国,刘承军,姜茂发.高硫铁矿氧化焙烧过程中硫的迁移行为[J].工程建设,2025,50(6):84-90

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  • 收稿日期:2024-11-13
  • 最后修改日期:2025-09-12
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  • 在线发布日期: 2025-11-16
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