难选铁尾矿富氢磁化焙烧中重金属的转化迁移机制
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梁永钊(2000—),男,硕士研究生,从事尾矿资源化利用方面的研究。

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X705;TF046;TD926

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国家自然科学基金资助项目(22476029); 广东省自然科学基金资助项目(2024A1515010315)


Transformation and migration mechanisms of heavy metals during hydrogen-rich magnetization roasting of refractory iron tailings
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    摘要:

    难选铁尾矿磁化焙烧中低含量重金属的迁移转化是影响磁铁精矿品质和尾渣综合利用的关键因素。本文以大宝山铁尾矿为对象,利用不同用量市政污泥作为还原剂,结合BCR连续提取、SEM-Mapping元素分布等研究手段,系统考察磁化焙烧过程中Cu、Zn、Pb的赋存状态演化与迁移行为。结果表明:原矿中Cu、Zn、Pb主要以同晶替代、包裹连生形式赋存于褐铁矿,在磁化焙烧中重金属存在向硫化矿相、铁及其氧化物相、铁橄榄石及脉石相的多路径迁移及转化。Cu随褐铁矿还原向磁铁矿迁移; Zn与石英反应生成硅酸铁,稳定赋存于脉石相; Pb随水磷铁铅石、砷铅铁矿的分解,向铁相与脉石相发生迁移。还原剂用量影响迁移路径,当用量超过25%时过还原反应加剧,硫化路径受抑制,更多重金属迁移至铁橄榄石相。后续分选中,浮选可富集硫化相中重金属,Cu、Zn、Pb富集倍数达1.4、2.2、3.7;磁选效率受铁橄榄石磁性影响,当污泥添加量为30%时,Cu、Zn、Pb去除率提高至20.55%、48.08%、47.84%。本研究结论可为难选铁尾矿“脱硫-除杂-提铁”协同工艺优化提供理论依据。

    Abstract:

    The migration and transformation of low-content heavy metals during the magnetization roasting of refractory iron tailings are key factors affecting the quality of magnetite concentrate and the comprehensive utilization of tailings. In this paper,Dabaoshan iron tailings was studied with municipal sludge of different consumption as a reducing agent and in combination of study methods such as BCR sequential extraction and SEM-Mapping elemental distribution,to systematically investigate the evolution of occurrence states and migration behaviors of Cu,Zn,and Pb during magnetization roasting. The results show that in the raw ore,Cu,Zn,and Pb primarily are hoisting in limonite through isomorphic substitution and encapsulated intergrowth. During magnetization roasting,heavy metals undergo multi-path migration and transformation into sulfide phases,iron and its oxide phases,fayalite,and gangue phases.Cu migrates to magnetite as limonite is reduced;Zn reacts with quartz to form iron silicate,stablizing within the gangue phase; Pb migrates to iron and gangue phases following the decomposition of drugmanite and carminite.The consumption of the reducing agent influences the migration path.When the dosage exceeds 25%,over-reduction intensifies,inhibiting sulfide path and causing more heavy metals to migrate to the fayalite phase. In subsequent separation processes,flotation can enrich heavy metals in sulfide phases,with enrichment factors of Cu,Zn,and Pb reaching 1.4,2.2,and 3.7,respectively. Magnetic separation efficiency is affected by the magnetic properties of fayalite. When the sludge dosage is 30%,the removal rates of Cu,Zn,and Pb increased to 20.55%,48.08%,and 47.84%,respectively. The findings of this study can provide a theoretical basis for optimizing the collaborative process of“desulfurization,impurity removal, and iron extraction”in refractory iron tailings.

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梁永钊,宁寻安,胡兵,张鼎元,邓金环,王逸,何峣.难选铁尾矿富氢磁化焙烧中重金属的转化迁移机制[J].工程建设,2025,50(6):91-100

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  • 收稿日期:2024-06-09
  • 最后修改日期:2025-04-16
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  • 在线发布日期: 2025-11-16
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